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Electrochemical Oscillations and Chaos on Macro- and Microscales: Phase Diffusion, Synchronization, and Pacemaker Design
Electrochemical Oscillations and Chaos on Macro- and Microscales: Phase Diffusion, Synchronization, and Pacemaker Design
By Dr. Istvan Z. Kiss
Saint Louis University Department of Chemistry
Thu, Dec 3, 2009 2:30 PM
Location: Lopata 101
Abstract:
Complex chemical and biological systems exhibit dynamic self-organization with emergent properties depending both on the behavior of the constituent parts and the types and extent of their interactions. We introduce the subject of chemical complexity through the description of macroscale and microscale electrochemical oscillations that occur on multi-particle electrodes.
In the presentation, electrochemical oscillations are described by using the concept of cycle phase and determine how the frequency and precision of the current oscillations on a single electrode depends on resistance and temperature, and how the extent of interactions affects periodic and chaotic synchronization patterns on electrode arrays.
With the use of phase models, a general methodology for the control of dynamic states to desired states in populations of rhythmic units is presented.
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